Product ID:CALCO UNLEADED GASOLINE
MSDS Date:01/23/1992
FSC:9130
NIIN:00-148-7102
MSDS Number: BPNVF

CHEVRON ENVIRONMENTAL HEALTH CENTER INC.

15299 SAN PABLO AVE.
RICHMOND, CA 94804
US

Emergency Phone: 800-457-2022

Info Phone: 800-582-3835

Cage: 0AHD1

CHEVRON ENVIRONMENTAL HEALTH CENTER INC

4054 RICHMOND, CA 94804 US

Telephone: 800-582-3835

Cage: 0AHD1

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 1-5%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 5-15%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 5-15%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

MAY CONTAIN METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 10% MAX

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ADDITIVES AND DYE

Fraction By Weight: <0.1%

LEAD (SARA III) (AS LEAD ALKYL)

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: .05%G/GL

OSHA PEL 0.05 MG/M3;1910.1025

ACGIH TLV: 0.15 MG/M3;DUST 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:TLV: 300 PPM (8-HOUR)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES-EYE IRRITATION MAY RESULT FROM
CONTACT. SKIN-PROLONGED OR FREQUENTLY REPEATED CONTACT MAY CAUSE
SKIN TO DEFAT. INHALATION-PROLONGED OR REPEATED BREATHING OF
GASOLINE VAPORS MAY BE HARMFUL. INGEST ION-THIS MATERIAL IS
EXPECTED TO BE ONLYSLIGHTLY TOXIC BY INGESTION.
Explanation of Carcinogenicity:LONG-TERM EXPOSURE TO VAPOR HAS CAUSED
CANCER IN LABORATORY ANIMALS. CONTAINS LEAD (AS LEAD ALKYL).
Effects of Overexposure:EYES: PAIN, TEARS, SWELLING, REDNESS, BLURRED
VISION. SKIN: DRYNESS AND CRACKING. INHALE: HEADACHE, DIZZINESS,
LOSS OF APPETITE AND LOSS OF CORDINATION. HIGH CONCENTRATIONS MAY
CAUSE LOSS OF CONSCIOUS NESS, COMA AND DEATH. INGESTION MAY CAUSE
THE SAME SYMPTOMS AS INHALING ALONG WITH LUNG DAMAGE AND DEATH.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:EYE-FLUSH IMMEDIATELY WITH FRESH WATER FOR AT LEAST 15 MIN.
IF IRRITATION PERSISTS, SEE A DOCTOR. SKIN-NO FIRST AID REQUIRED.
HOWEVER, WASH SKIN THOROUGHLY WITH SOAP & WATER. INHALATION-IF
SYMPTOMS OC CUR, MOVE THE PERSON TO FRESH AIR. IF STOP BREATHING,
DO CPR. CALL A DOCTOR. INGESTION-IF SWALLOWED, DO NOT MAKE PERSON
VOMIT. CALL A DOCTOR IMMEDIATELY.

Flash Point Method:PMCC
Flash Point:<-49F,<-45C
Autoignition Temp:Autoignition Temp Text:NDA
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:FIREFIGHTING FOAM: ALCOHOL RESISTANT TYPE (AR)
AFFF, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING GASOLINE FIRES. THIS
PRODUCT PRESENTS AN EXTREME FIRE HAZARD.
Unusual Fire/Explosion Hazard:LIQUID VERY QUICKLY EVAPORATES, EVEN AT
LOW TEMPERATURES, AND FORMS VAPOR WHICH CAN CATCH FIRE AND BURN
WITH EXPLOSIVE VIOLENCE. EXTINGUISH ALL IGNITION SOURCES

Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION IN VICINITY
OF SPILL OR RELEASED VAPOR. CLEAN UP SMALL SPILLS USING APPROPIATE
TECHNIQUES SUCH AS SORBENT MATERIALS OR PUMPING. WHERE FEASIBLE &
APPROPIATE, REMOVE CO NTAMINATED SOIL. FOLLOW REPORTING PROCEDURES.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:DO NOT USE OR STORE NEAR FLAME, SPARKS
OR HOT SURFACES. USE & STORE ONLY IN COOL, WELL VENTILATED AREA.
KEEP CONTAINER CLOSED.
Other Precautions:DO NOT TRANSFER LIQUID TO AN UNLABELED CONTAINER.
NEVER SIPHON GASOLINE BY MOUTH. READ AND OBSERVE ALL PRECAUTIONS ON
PRODUCT LABEL. USE ONLY AS A MOTOR FUEL. DO NOT USE FOR CLEANING,
PRESSURE APPLIAN CE FUEL, OR ANY OTHER SUCH USE.

Respiratory Protection:AVOID PROLONGED BREATHING OF VAPOR BY USING
APPROVED RESPIRATORY PROTECTION. IN OPEN AREAS, VENTILATION IS
USUALLY ADEQUATE TO PREVENT PROLONGED BREATHING OF HIGH GASOLINE
VAPORS CONCENTRATIONS.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED ARES.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL SAFETY GOGGLES.
Other Protective Equipment:SKIN CONTACT SHOULD BE MINIMIZED BY WEARING
PROTECTIVE CLOTHING. EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.

HCC:F1
Boiling Pt:B.P. Text:25-225C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:5-15 PSI
Vapor Density:3-4 AIR=1
Spec Gravity:0.7-0.8
Viscosity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:INSOLUBLE
Appearance and Odor:ORANGE TO BRONZE LIQUID.
Percent Volatiles by Volume:99+%
Corrosion Rate:UNKNOWNN

Stability Indicator/Materials to Avoid:YES
MAY REACT WITH STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES,
PILOT LIGHTS, WELDING EQUIPMENT, ELECTRICAL MOTORS AND SWITCHES.
Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE
& WATER VAPORS; INCOMPLETE COMBUSTION CAN PRODUCE CARBON MONOXIDE.

Waste Disposal Methods:PLACE CONTAMINATED MATERIALS IN DISPOSABLE
CONTAINERS & DISPOSE OF IN A MANNER CONSISTENT WITH APPLICABLE
REGULATIONS. CONTACT LOCAL ENVIRONMENTAL HEALTH AUTHORITIES FOR
APPROVED DISPOSAL OF THIS MATE RIAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.